CHEM 558 - Electrochemistry Syllabus Spring 2007
Frank
Cheng, Renfrew 26A,
Office
Hours: M&W 2:30 4:30
PM
Required Text: Electrochemical Methods: Fundamentals and Applications, 2nd ed., AJ Bard; LR Faulkner
NEW (03-31-07) Homework to be turned in for credit
|
Topics |
|
Book Chapter and Section
|
| Thermodynamics
of Electrochemical Cells |
Nernst Equation |
1.1
pages 1-9 & 2.1 2.1.6 |
| Reference
Electrodes |
2.1.7 |
|
| Ion-selective
Electrodes |
2.4 |
|
| Advanced
Aspects of Nernst Eqn |
Lecture
Notes |
|
| Pourbaix
Diagrams |
Lecture
Notes |
|
| Homework
Set 1 |
Answers | |
|
|
|
|
| Heterogeneous
Kinetics |
Introduction |
3.1
3.2 |
| ButlerVolmer
Kinetics |
3.3
3.5 |
|
| Marcus
Theory |
3.6 |
|
| Homework
Set 2 |
Answers | |
| |
|
|
| Controlled
Potential Methods |
Introduction |
5.1 |
| Potential
Step Diffusion Control |
5.2
5.4 |
|
| Mass
Transport Diffusion, Migration and Convection |
4.1
4.4 |
|
| Potential Step Kinetic Control |
5.5
5.6 |
|
| Chronocoulometry |
5.8 |
|
| Polarography |
7.1
7.2 |
|
| Pulse
Polarography/Voltammetry |
7.3
7.4 |
|
| Stripping
Analysis |
11.8 |
|
|
|
||
| |
|
|
| Cyclic
Voltammetry |
Cyclic
Voltammetry |
6.1
6.7 |
| Emphasis
on Coupled Homogeneous Reactions |
12.1
12.7 |
|
| Thin-Layer Cells | ||
| Ultramicroelectrodes | ||
| Homework
Set 4 |
Answers | |
| Electroanalytical
Techniques |
Hydrodynamic Methods |
9.1 9.7, 11.6 |
|
Bulk Electrolysis |
11.1 11.4 |
|
| AC Techniques | Applications to Batteries and Fuel Cells | Read Chapter 10 |
| Recent Topics | Time Permitting | |
| Oral Presentations | Based on pre-approved topics, 25 minutes each using multimedia equipment |
Exam I: (100 points) February 14
Final Exam (100 points)
Oral Presentation (50 points)
Homework problems (100 points)
A
homework problem set will be distributed at the course web site for each topic.
Each set will have one to three problems in which you will be asked to solve on
your own. These problems will be graded for course credit. The others problems
will not be graded and you will be able to work on these problems with your
peers.